Search results for " mixture"

Advances in photochemical and electrochemical incorporation of sulfur dioxide for the synthesis of value-added compounds.

2021

Organic photochemistry and electrochemistry currently receive tremendous attention in organic synthesis as both techniques enable the reagent-less activation of organic molecules without using expensive and hazardous redox reagents. The incorporation of SO2 into organic molecules is a relatively modern research topic, which likewise gains immense popularity since the discovery of the SO2 surrogate DABSO. Sulfur-containing organic molecules are omnipresent in pharmaceuticals and agrochemicals. This review covers the recent progress in electrochemical and photochemical methodologies for the incorporation and uses of SO2 in the synthesis of value-added compounds. Additionally, different work t…

Chiral and Racemic Spin Crossover Polymorphs in a Family of Mononuclear Iron(II) Compounds

2017

[EN] Understanding the origin of cooperativity and the equilibrium temperature of transition (T1/2) displayed by the spin-crossover (SCO) compounds as well as controlling these parameters are of paramount importance for future applications. For this task, the occurrence of polymorphism, presented by a number of SCO complexes, may provide deep insight into the influence of the supramolecular organization on the SCO behavior. In this context, herein we present a novel family of mononuclear octahedral FeII complexes with formula cis- [Fe(bqen)(NCX)2], where bqen is the chelating tetradentate ligand N,N¿-bis(8-quinolyl)ethane-1,2-diamine and X = S, Se. Depending on the preparation method, these…

Hybrid GMP–polyamine hydrogels as new biocompatible materials for drug encapsulation

2020

Here we present the preparation and characterization of new biocompatible materials for drug encapsulation. These new gels are based on positively charged [1+1] 1H-pyrazole-based azamacrocycles which minimise the electrostatic repulsions between the negatively charged GMP molecules. Rheological measurements confirm the electroneutral hydrogel structure as the most stable for all the GMP-polyamine systems. Nuclear magnetic resonance (NMR) was employed to investigate the kinetics of the hydrogel formation and cryo-scanning electron microscopy (cryo-SEM) was used to obtain information about the hydrogel morphology, which exhibited a non-homogeneous structure with a high degree of cross-linking…

Synthesis and structural properties of hexaaza[5]helicene containing two [1,2,3]triazolo[1,5-a]pyridine moieties

2013

Abstract We have synthesized a novel hexaaza[5]helicene in a straightforward way from neocuproine. The crystal structure has been elucidated with direct-space strategy TALP which demonstrates the power of the powder X-ray diffraction technique. In this crystal structure it is possible to see an interplanar angle of 33(1)° between the two triazolopyridine rings. The centrosymmetric crystal structure is a racemic mixture, but the resolution was not possible due to a ring-chain isomerization in a solution that produces a dynamic racemization.

Chemical aging of atmospheric mineral dust during transatlantic transport

2016

Abstract. Transatlantic dust transport has many implications for the atmosphere, ocean and climate. We present a modeling study on the impact of the key processes (dust emissions flux, convection and dust aging parameterizations) that control the transatlantic dust transport. Typically, the Inter-Tropical Convergence Zone (ITCZ) acts as a barrier for the meridional dust transport. To characterize the dust outflow over the Atlantic Ocean, we address two regional phenomena: (i) dust interactions with the ITCZ (DIZ) and (ii) the adjacent dust transport over the Atlantic Ocean (DTA). In the DTA zone, the dust loading shows a steep and linear gradient westward over the Atlantic Ocean where parti…

2021

Abstract Contaminated soils are lands in Europe deemed less favourable for conventional agriculture. To overcome the problem of their poor fertility, bio-fertilization could be a promising approach. Soil inoculation with a choice of biological species (e.g. earthworm, mycorrhizal fungi, diazotroph bacteria) can be performed in order to improve soil properties and promote nutrients recycling. However, questions arise concerning the dynamics of the contaminants in an inoculated soil. The aim of this study was to highlight the soil-plant-earthworm interactions in the case of a slightly contaminated soil. For this purpose, a pot experiment in controlled conditions was carried out during 2 month…

Evidence of organic contamination in urban soils of Cotonou town (Benin).

2012

14 pages; International audience; In Cotonou (Benin), growth of the population leads to an excessive use of natural resources, inducing organic contaminations. Surface soils collected in the town, were extracted and fractionated by liquid chromatography in three families: aliphatic, aromatic hydrocarbons and polar fractions. Each fraction was characterized by gas chromatography-mass spectrometry. All the results show that an anthropogenic input exists (waste oils). Indeed, aliphatic hydrocarbons have specific markers emphasizing the presence of petrogenic products: UCM (unresolved complex mixture), specific distribution of pentacyclic triterpane. However, specific molecular biomarkers revea…

Soil physicochemical and microbial drivers of temperature sensitivity of soil organic matter decomposition under boreal forests

2020

Abstract Soil organic matter (SOM) in boreal forests is an important carbon sink. The aim of this study was to assess and to detect factors controlling the temperature sensitivity of SOM decomposition. Soils were collected from Scots pine, Norway spruce, silver birch, and mixed forests (O horizon) in northern Finland, and their basal respiration rates at five different temperatures (from 4 to 28 °C) were measured. The Q10 values, showing the respiration rate changes with a 10 °C increase, were calculated using a Gaussian function and were based on temperature-dependent changes. Several soil physicochemical parameters were measured, and the functional diversity of the soil microbial communit…

Jumping on the Edge—First Evidence for a 2 × 6-meric Hemocyanin in Springtails

2019

Hemocyanins are respiratory dioxygen carrier proteins found in many arthropods including ancient terrestrial species such as spiders and scorpions as well as marine horseshoe crabs. As hemocyanins are highly conserved in this lineage, it is possible to observe an evolutionary descent through its subunits and their overall structure. Unfortunately, little is known about the structure and function of hexapod hemocyanins. Using recent springtail taxa (Collembola) as models for basal hexapods, and the help of electron microscopy, light scattering, SDS PAGE, and Western blot, we could demonstrate for the first time the presence of 2 × 6-meric hemocyanins in the hemolymph of hexapods. The quatern…

First extensive characterization of the venom gland from an egg parasitoid: structure, transcriptome and functional role.

2018

The venom gland is a ubiquitous organ in Hymenoptera. In insect parasitoids, the venom gland has been shown to have multiple functions including regulation of host immune response, host paralysis, host castration and developmental alteration. However, the role played by the venom gland has been mainly studied in parasitoids developing in larval or pupal hosts while little is known for parasitoids developing in insect eggs. We conducted the first extensive characterization of the venom of the endoparasitoid Ooencyrtus telenomicida (Vassiliev), a species that develops in eggs of the stink bug Nezara viridula (L.). In particular we investigated the structure of the venom apparatus, its functio…